A locally adaptive time-stepping algorithm for\ud petroleum reservoir simulations

An algorithm for locally adapting the step-size for large scale finite volume simulations of multi-phase flow in petroleum reservoirs is suggested which allows for an “all-in-one” implicit calculation of behaviour over a very large time scale. Some numerical results for simple two-phase flow in one space dimension illustrate the promise of the algorithm, which has also been applied to very simple 3D cases. A description of the algorithm is presented here along with early results. Further development of the technique is hoped to facilitate useful scaling properties

Taking a “Deep Dive”: What Only a Top Leader Can Do

Unlike most historical accounts of strategic change inside large firms, empirical research on strategic management rarely uses the day-to-day behaviors of top executives as the unit of analysis. By examining the resource allocation process closely, we introduce the concept of a deep dive, an intervention when top management seizes hold of the substantive content of a strategic initiative and its operational implementation at the project level, as a way to drive new behaviors that enable an organization to shift its performance trajectory into new dimensions unreachable with any of the previously described forms of intervention. We illustrate the power of this previously underexplored change mechanism with a case study, in which a well-established firm overcame barriers to change that were manifest in a wide range of organizational routines and behavioral norms that had been fostered by the pre-existing structural context of the firm.Strategic Change, Resource Allocation Process, Top-down Intervention

The extreme flare in III Zw 2: Evolution of a radio jet in a Seyfert galaxy

A very detailed monitoring of a radio flare in the Seyfert I galaxy III Zw 2 with the VLA and the VLBA is presented. The relative astrometry in the VLBA observations was precise on a level of a few microarcseconds. Spectral and spatial evolution of the source are closely linked and these observations allowed us to study in great detail a textbook example of a synchrotron self-absorbed jet. We observe a phase where the jet gets frustrated, without expansion and no spectral evolution. Then the jet breaks free and starts to expand with apparent superluminal motion. This expansion is accompanied by a strong spectral evolution. The results are a good confirmation of synchrotron theory and equipartition for jets.Comment: Astronomy & Astrophysics, accepted, 11 pages, 14 Figures, also available at http://www.jive.nl/~brunthal/pub.shtm

In-Situ Colloidal MnO2 Deposition and Ozonation of 2,4-Dinitrotoluene

Laboratory experiments are presented that demonstrate a novel in situ semipassive reactive barrier for the degradation of 2,4 dinitrotoluene created by coating aquifer surfaces by deposition of colloidal MnO2, which catalyzes ozone degradation and enhances contaminant oxidation. Ozone is added to the reactive barrier and is transported through the zone with the contaminants by existing hydraulic gradients. The communication presents the preliminary laboratory investigation demonstrating the viability of this method. Studies were conducted by coating Ottawa sand with colloidal MnO2. Results show that concentrations of MnO2 in the range of 0.2 mg/g can be deposited with no measurable change in hydraulic conductivity, that there is significant coverage of the sand material by MnO2, and the deposition was not reversible under a wide range of chemical conditions. Ozonation of 2,4-dinitrotoluene in the presence of MnO2- coated sand was demonstrated to result in pseudo-first-order degradation kinetics with respect to DNT with half-lives ranging from 28 to 22 min (at pH 6 and 7, respectively), approximately 25% faster than experiments performed in the absence of MnO2

Interoperability in the GENESIS 3.0 Software Federation : the NEURON Simulator as an Example

© 2013 Cornelis et al; licensee BioMed Central Ltd. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.Poster presented at CNS 2013Non peer reviewe

The Rotation Measure and 3.5mm Polarization of Sgr A*

We report the detection of variable linear polarization from Sgr A* at a wavelength of 3.5mm, the longest wavelength yet at which a detection has been made. The mean polarization is 2.1 +/- 0.1% at a position angle of 16 +/- 2 deg with rms scatters of 0.4% and 9 deg over the five epochs. We also detect polarization variability on a timescale of days. Combined with previous detections over the range 150-400GHz (750-2000 microns), the average polarization position angles are all found to be consistent with a rotation measure of -4.4 +/- 0.3 x 10^5 rad/m^2. This implies that the Faraday rotation occurs external to the polarized source at all wavelengths. This implies an accretion rate ~0.2 - 4 x 10^-8 Msun/yr for the accretion density profiles expected of ADAF, jet and CDAF models and assuming that the region at which electrons in the accretion flow become relativistic is within 10 R_S. The inferred accretion rate is inconsistent with ADAF/Bondi accretion. The stability of the mean polarization position angle between disparate polarization observations over the frequency range limits fluctuations in the accretion rate to less than 5%. The flat frequency dependence of the inter-day polarization position angle variations also makes them difficult to attribute to rotation measure fluctuations, and suggests that both the magnitude and position angle variations are intrinsic to the emission.Comment: Ap.J.Lett. accepte

Synthesis and Applications of Rhodacyclopentanones Derived From C-C Bond Activation

Rhodacyclopentanones, an “sp(3)-rich” class of metallacycle, underpin an emerging range of catalytic methodologies for the direct generation of complex scaffolds. This review highlights strategies for accessing rhodacyclopentanones (and related species) by C-C bond activation of cyclobutanones or cyclopropanes. The scope and mechanism of methodologies that exploit these activation modes is outlined